Synthesis and reduction kinetics of sterically shielded pyrrolidine nitroxides.
نویسندگان
چکیده
A series of sterically shielded pyrrolidine nitroxides were synthesized, and their reduction by ascorbate (vitamin C) indicate that nitroxide 3, a tetraethyl derivative of 3-carboxy-PROXYL, is reduced at the slowest rate among known nitroxides, i.e., at a 60-fold slower rate than that for 3-carboxy-PROXYL.
منابع مشابه
Synthesis of Unnatural Amino Acids Functionalized with Sterically Shielded Pyrroline Nitroxides
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ورودعنوان ژورنال:
- Organic letters
دوره 14 20 شماره
صفحات -
تاریخ انتشار 2012